Picture-in-Picture icon OfficeOne Picture-in-Picture Presentation

Troubleshooting
Most probably, the issue would be that Picture-in-Picture Presentation has been disabled. In such a case, you can re-enable Picture-in-Picture Presentation using the following steps:
PowerPoint 2019, 2016, 2013, 2010 PowerPoint 2007
  1. Select the File tab or press Alt+F key combination.
  2. Click Options button in the left pane
  3. Select Add-Ins in the left pane.
  4. Select Disabled Items in the Manage box and click Go... button.
  5. Select Picture-in-Picture Presentation and click Enable button.
  6. Click Close to dismiss the dialog box.
  1. Select the Office Button or press Alt+F key combination.
  2. Click PowerPoint Options button.
  3. Select Add-Ins in the left pane.
  4. Select Disabled Items in the Manage box and click Go... button.
  5. Select Picture-in-Picture Presentation and click Enable button.
  6. Click Close to dismiss the dialog box.
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